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Capillary gas chromatography of polychlorinated benzonitriles (PCBN)

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PCBN.pdf (83.06Kb)

peer-reviewed

Erstveröffentlichung
1997-12
Authors
Mittermaier, Bernhard
Ballschmiter, Karlheinz
Wissenschaftlicher Artikel


Published in
Fresenius' Journal of Analytical Chemistry ; 359 (1997), 7-8. - S. 561-564. - ISSN 0937-0633
Link to original publication
https://dx.doi.org/10.1007/s002160050632
Faculties
Fakultät für Naturwissenschaften
Institutions
Abteilung für Analytische Chemie und Umweltchemie
Document version
accepted version
Abstract
Polychlorinated benzonitriles (PCBN) are products of combustion chemistry and can be emitted from municipal waste incinerators. Their possible relevance to environmental chemistry has not previously been described, with the exception of the herbicide 2,6-dichlorobenzonitrile. The isomer-specific separation and detection of the 19 PCBN congeners is performed by HRGC-ECD and HRGC-MSD. Commercially unavailable congeners were synthesized from chlorinated anilines and benzaldehydes. Retention data on three different stationary phases are given. Structure-retention relationships are discussed. A structure-specific systematic numbering of the 19 PCBN congeners is suggested.
Subject headings
[GND]: PCBN | Kapillargaschromatographie | Ökologische Chemie
[LCSH]: Environmental chemistry | Chromatographic analysis
[DDC subject group]: DDC 540 / Chemistry & allied sciences
License
CC BY 4.0 International
https://creativecommons.org/licenses/by/4.0/

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DOI & citation

Please use this identifier to cite or link to this item: http://dx.doi.org/10.18725/OPARU-43708

Mittermaier, Bernhard; Ballschmiter, Karlheinz (2022): Capillary gas chromatography of polychlorinated benzonitriles (PCBN). Open Access Repositorium der Universität Ulm und Technischen Hochschule Ulm. http://dx.doi.org/10.18725/OPARU-43708
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