Show simple item record

AuthorDigennaro, Angeladc.contributor.author
Date of accession2017-02-01T09:31:40Zdc.date.accessioned
Available in OPARU since2017-02-01T09:31:40Zdc.date.available
Year of creation2016dc.date.created
Date of first publication2017-02-01dc.date.issued
AbstractThe aim of this thesis was to synthesize new asymmetric pi-conjugated A-B systems, which are able to self-assemble in chiral suprastructures due to the presence of a single amino acid and to investigate them with respect to their self-assembling behaviour in solution and in the solid state. The self-assembly process of the synthesized oligothiophenes was investigated in solution by UV/Vis, fluorescence, and CD-spectroscopy. The optical and chiroptical properties pointed out to the formation of aggregates in which the pi-conjugated systems interact with each other confirming the influence of the proline scaffold. Additionally, investigation of the self-assembly properties in the solid state was performed by AFM and TEM: the formation of micelles was observed.dc.description.abstract
Languageendc.language.iso
PublisherUniversität Ulmdc.publisher
LicenseStandarddc.rights
Link to license texthttps://oparu.uni-ulm.de/xmlui/license_v3dc.rights.uri
KeywordProline-Quaterthiophene hybriddc.subject
KeywordSynthesisdc.subject
KeywordSelf-assembly in solutiondc.subject
KeywordSelf-assembly in the solid statedc.subject
KeywordChiroptical propertiesdc.subject
KeywordElectrochemical propertiesdc.subject
Dewey Decimal GroupDDC 540 / Chemistry & allied sciencesdc.subject.ddc
LCSHOligothiophenesdc.subject.lcsh
LCSHPolymers; Optical propertiesdc.subject.lcsh
LCSHSelf assembly (Chemistry)dc.subject.lcsh
TitleProline-Quaterthiophene hybrids: Synthesis and self-assemblydc.title
Resource typeDissertationdc.type
Date of acceptance2016-07-06dcterms.dateAccepted
RefereeBäuerle, Peterdc.contributor.referee
RefereeWeil, Tanjadc.contributor.referee
DOIhttp://dx.doi.org/10.18725/OPARU-4212dc.identifier.doi
PPN879892471dc.identifier.ppn
URNhttp://nbn-resolving.de/urn:nbn:de:bsz:289-oparu-4251-7dc.identifier.urn
GNDChemische Synthesedc.subject.gnd
FacultyFakultät für Naturwissenschaftenuulm.affiliationGeneral
InstitutionInstitut für Organische Chemie II und Neue Materialienuulm.affiliationSpecific
InstitutionInstitut für Organische Chemie III (Makromolekulare Chemie und Organische Materialien)uulm.affiliationSpecific
Shelfmark print versionW: W-H 14.988uulm.shelfmark
Grantor of degreeFakultät für Naturwissenschaftenuulm.thesisGrantor
DCMI TypeTextuulm.typeDCMI
TypeErstveröffentlichunguulm.veroeffentlichung
CategoryPublikationenuulm.category
University Bibliographyjauulm.unibibliographie


Files in this item

Thumbnail

This item appears in the following Collection(s)

Show simple item record