Towards artificial photosynthesis with molecular photocatalysts : From photocatalysis in biological media to optimization of light-driven organometallic catalysis
Erstveröffentlichung
2022-02-22Referee
Rau, Svenvon Delius, Max
Campagna, Sebastiano
Dissertation
Faculties
Fakultät für NaturwissenschaftenInstitutions
Institut für Anorganische Chemie I (Materialien und Katalyse)Institut für Organische Chemie I
Abstract
The conversion of solar energy into chemical bond energy represents one of the most important scientific goals in the 21st century. By investigating the properties of a heterodinuclear RuRh photocatalyst, along with other molecules, this thesis strives to develop detailed understanding of (light-activated) mechanisms limiting photocatalytic processes as well as to utilize this knowledge to explore new catalytic applications.
Date created
2020
DFG Project THU
TRR 234 / CATALIGHT / Lichtgetriebene molekulare Katalysatoren in hierarchisch strukturierten Materialien / DFG / 364549901
Cumulative dissertation containing articles
• Product Selectivity in Homogeneous Artificial Photosynthesis Using [(bpy)Rh(Cp*)X]n+-Based Catalysts; Alexander K. Mengele, Sven Rau, Inorganics 2017, 5, 25. http://doi.org/10.3390/inorganics5020035
• Generation of a stable supramolecular hydrogen evolving photocatalyst by alteration of the catalytic center; Alexander K. Mengele, Simon Kaufhold, Carsten Streb, Sven Rau, Dalton Trans. 2016, 45, 6612-6618. http://doi.org/10.1039/C6DT00130K
• Coupling Molecular Photocatalysis to Enzymatic Conversion; Alexander K. Mengele, Gerd M. Seibold, Bernhard J. Eikmanns, Sven Rau, ChemCatChem 2017, 9, 4369-4376. http://doi.org/10.1002/cctc.201701232
• Unraveling the Light-Activated Reaction Mechanism in a Catalytically Competent Key Intermediate of a Multifunctional Molecular Catalyst for Artificial Photosynthesis; Linda Zedler, Alexander K. Mengele, Karl Michael Ziems, Ying Zhang, Maria Wächtler, Stefanie Gräfe, Torbjörn Pascher, Sven Rau, Stephan Kupfer, Benjamin Dietzek, Angew. Chem. 2019, 131, 13274-13282; Angew. Chem. – Int. Ed. 2019, 58, 13140-13148. http://doi.org/10.1002/anie.201907247
• The Metallic Traveler: Formate- and Photoinduced Regioselective Phenanthroline Deuterations via Reductively Activated RhCp* Centers; Alexander K. Mengele, Sven Rau, Organometallics 2020, 39, 2739-2748. http://doi.org/10.1021/acs.organomet.0c00341
• Switching the Mechanism of NADH Photooxidation by Supramolecular Interactions; Alexander K. Mengele, Dominik Weixler, Avinash Chettri, Maite Maurer, Fabian L. Huber, Gerd M. Seibold, Benjamin Dietzek, Bernhard J. Eikmanns, Sven Rau, Chem. – A Eur. J. 2021, 27. http://doi.org/10.1002/chem.202103029
• Transforming Escherichia coli Proteomembranes into Artificial Chloroplasts Using Molecular Photocatalysis; Alexander K. Mengele, Dominik Weixler, Sebastian Amthor, Bernhard J. Eikmanns, Gerd M. Seibold, Sven Rau, Angew. Chem. Int. Ed. 2021, e202114842. http://doi.org/10.1002/anie.202114842
• Molecular Scylla and Charybdis ― Maneuvering between pH-sensitivity and excited state localization in ruthenium bi(benz)imidazole complexes; Alexander K. Mengele, Carolin Müller, Djawed Nauroozi, Stephan Kupfer, Benjamin Dietzek, Sven Rau, Inorg. Chem. 2020, 59, 12097–12110. http://doi.org/10.1021/acs.inorgchem.0c01022
• Generation of a stable supramolecular hydrogen evolving photocatalyst by alteration of the catalytic center; Alexander K. Mengele, Simon Kaufhold, Carsten Streb, Sven Rau, Dalton Trans. 2016, 45, 6612-6618. http://doi.org/10.1039/C6DT00130K
• Coupling Molecular Photocatalysis to Enzymatic Conversion; Alexander K. Mengele, Gerd M. Seibold, Bernhard J. Eikmanns, Sven Rau, ChemCatChem 2017, 9, 4369-4376. http://doi.org/10.1002/cctc.201701232
• Unraveling the Light-Activated Reaction Mechanism in a Catalytically Competent Key Intermediate of a Multifunctional Molecular Catalyst for Artificial Photosynthesis; Linda Zedler, Alexander K. Mengele, Karl Michael Ziems, Ying Zhang, Maria Wächtler, Stefanie Gräfe, Torbjörn Pascher, Sven Rau, Stephan Kupfer, Benjamin Dietzek, Angew. Chem. 2019, 131, 13274-13282; Angew. Chem. – Int. Ed. 2019, 58, 13140-13148. http://doi.org/10.1002/anie.201907247
• The Metallic Traveler: Formate- and Photoinduced Regioselective Phenanthroline Deuterations via Reductively Activated RhCp* Centers; Alexander K. Mengele, Sven Rau, Organometallics 2020, 39, 2739-2748. http://doi.org/10.1021/acs.organomet.0c00341
• Switching the Mechanism of NADH Photooxidation by Supramolecular Interactions; Alexander K. Mengele, Dominik Weixler, Avinash Chettri, Maite Maurer, Fabian L. Huber, Gerd M. Seibold, Benjamin Dietzek, Bernhard J. Eikmanns, Sven Rau, Chem. – A Eur. J. 2021, 27. http://doi.org/10.1002/chem.202103029
• Transforming Escherichia coli Proteomembranes into Artificial Chloroplasts Using Molecular Photocatalysis; Alexander K. Mengele, Dominik Weixler, Sebastian Amthor, Bernhard J. Eikmanns, Gerd M. Seibold, Sven Rau, Angew. Chem. Int. Ed. 2021, e202114842. http://doi.org/10.1002/anie.202114842
• Molecular Scylla and Charybdis ― Maneuvering between pH-sensitivity and excited state localization in ruthenium bi(benz)imidazole complexes; Alexander K. Mengele, Carolin Müller, Djawed Nauroozi, Stephan Kupfer, Benjamin Dietzek, Sven Rau, Inorg. Chem. 2020, 59, 12097–12110. http://doi.org/10.1021/acs.inorgchem.0c01022
Subject headings
[GND]: Fotokatalyse | Photoredox-Katalyse | Ruthenium | Rhodium | Koordinationslehre[LCSH]: Photocatalysis
[Free subject headings]: Photobiokatalyse | Koordinationschemie
[DDC subject group]: DDC 540 / Chemistry & allied sciences
Metadata
Show full item recordDOI & citation
Please use this identifier to cite or link to this item: http://dx.doi.org/10.18725/OPARU-41880
Mengele, Alexander Klaus (2022): Towards artificial photosynthesis with molecular photocatalysts : From photocatalysis in biological media to optimization of light-driven organometallic catalysis. Open Access Repositorium der Universität Ulm und Technischen Hochschule Ulm. Dissertation. http://dx.doi.org/10.18725/OPARU-41880
Citation formatter >