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AutorEggers, Berenddc.contributor.author
Aufnahmedatum2016-03-29T14:00:55Zdc.date.accessioned
In OPARU verfügbar seit2016-03-29T14:00:55Zdc.date.available
Jahr der Erstellung2015dc.date.created
ZusammenfassungThe following thesis deals with the functionalization of bisterpyridine and terpyridine ligands, as well as their metal complexes to enable their use as novel platforms for the creation of three dimensional multivalent grid complex structures through supramolecular self organization. For this purpose a number of functionalized chalcones were synthesized and converted into the corresponding functionalized bisterpyridine or terpyridine ligands under either known or newly developed reaction conditions. A functional group interconversion approach enabled the introduction of several functional groups that were not available through the original synthesis. To allow for the attachment of complex molecules, a number of syntheses based on the CuAAC reaction were developed through which dyes, biomolecules and spacers could be attached to the ligand structure. In addition it was possible through a thermal Huisgen reaction to functionalize the finished metal complex and attach up to eight substituents in one step. Finally the synthesis of a terpyridine-bound tripeptide was successful, which forms fibrillar aggregates in an aqueous environment.dc.description.abstract
Sprachededc.language.iso
Verbreitende StelleUniversität Ulmdc.publisher
LizenzStandarddc.rights
Link zum Lizenztexthttps://oparu.uni-ulm.de/xmlui/license_v3dc.rights.uri
SchlagwortBis(terpyridine)dc.subject
SchlagwortGitterkomplexdc.subject
SchlagwortGrid complexdc.subject
SchlagwortMetal complexdc.subject
SchlagwortOligopyridinedc.subject
SchlagwortTerpyridinedc.subject
DDC-SachgruppeDDC 540 / Chemistry & allied sciencesdc.subject.ddc
LCSHHeterocyclic chemistrydc.subject.lcsh
LCSHMetal complexesdc.subject.lcsh
LCSHPyridinedc.subject.lcsh
LCSHSelf-assembly (Chemistry)dc.subject.lcsh
TitelFunktionalisierung von Gitterkomplexen und Gitterkomplexliganden auf Oligopyridin-Basisdc.title
RessourcentypDissertationdc.type
DOIhttp://dx.doi.org/10.18725/OPARU-3926dc.identifier.doi
PPN462841049dc.identifier.ppn
URNhttp://nbn-resolving.de/urn:nbn:de:bsz:289-vts-99299dc.identifier.urn
GNDGittererzeugungdc.subject.gnd
GNDLigand <Biochemie>dc.subject.gnd
GNDPyridinderivatedc.subject.gnd
FakultätFakultät für Naturwissenschaftenuulm.affiliationGeneral
Datum der Freischaltung2016-03-29T12:23:01Zuulm.freischaltungVTS
Peer-Reviewneinuulm.peerReview
Signatur DruckexemplarW: W-H 14.651uulm.shelfmark
DCMI MedientypTextuulm.typeDCMI
VTS-ID9929uulm.vtsID
KategoriePublikationenuulm.category


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