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AuthorEggers, Berenddc.contributor.author
Date of accession2016-03-29T14:00:55Zdc.date.accessioned
Available in OPARU since2016-03-29T14:00:55Zdc.date.available
Year of creation2015dc.date.created
AbstractThe following thesis deals with the functionalization of bisterpyridine and terpyridine ligands, as well as their metal complexes to enable their use as novel platforms for the creation of three dimensional multivalent grid complex structures through supramolecular self organization. For this purpose a number of functionalized chalcones were synthesized and converted into the corresponding functionalized bisterpyridine or terpyridine ligands under either known or newly developed reaction conditions. A functional group interconversion approach enabled the introduction of several functional groups that were not available through the original synthesis. To allow for the attachment of complex molecules, a number of syntheses based on the CuAAC reaction were developed through which dyes, biomolecules and spacers could be attached to the ligand structure. In addition it was possible through a thermal Huisgen reaction to functionalize the finished metal complex and attach up to eight substituents in one step. Finally the synthesis of a terpyridine-bound tripeptide was successful, which forms fibrillar aggregates in an aqueous environment.dc.description.abstract
Languagededc.language.iso
PublisherUniversität Ulmdc.publisher
LicenseStandarddc.rights
Link to license texthttps://oparu.uni-ulm.de/xmlui/license_v3dc.rights.uri
KeywordBis(terpyridine)dc.subject
KeywordGitterkomplexdc.subject
KeywordGrid complexdc.subject
KeywordMetal complexdc.subject
KeywordOligopyridinedc.subject
KeywordTerpyridinedc.subject
Dewey Decimal GroupDDC 540 / Chemistry & allied sciencesdc.subject.ddc
LCSHHeterocyclic chemistrydc.subject.lcsh
LCSHMetal complexesdc.subject.lcsh
LCSHPyridinedc.subject.lcsh
LCSHSelf-assembly (Chemistry)dc.subject.lcsh
TitleFunktionalisierung von Gitterkomplexen und Gitterkomplexliganden auf Oligopyridin-Basisdc.title
Resource typeDissertationdc.type
DOIhttp://dx.doi.org/10.18725/OPARU-3926dc.identifier.doi
PPN855864346dc.identifier.ppn
URNhttp://nbn-resolving.de/urn:nbn:de:bsz:289-vts-99299dc.identifier.urn
GNDGittererzeugungdc.subject.gnd
GNDLigand <Biochemie>dc.subject.gnd
GNDPyridinderivatedc.subject.gnd
FacultyFakultät für Naturwissenschaftenuulm.affiliationGeneral
Date of activation2016-03-29T12:23:01Zuulm.freischaltungVTS
Peer reviewneinuulm.peerReview
Shelfmark print versionW: W-H 14.651uulm.shelfmark
DCMI TypeTextuulm.typeDCMI
VTS-ID9929uulm.vtsID
CategoryPublikationenuulm.category


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