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Ruthenium-Sulfonamid-Komplexe als Katalysatoren für Carbenübertragungsreaktionen

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179 Seiten
 
Veröffentlichung
2011-03-24
DOI
10.18725/OPARU-1900
Dissertation


Authors
Buck, Stefan
Faculties
Fakultät für Naturwissenschaften
License
Standard (Fassung vom 01.10.2008)
https://oparu.uni-ulm.de/xmlui/license_v2
Abstract
Ruthenium(I) complexes are a less costly alternative to the established rhodium catalysts in carbene transfer reactions. This type of ruthenium catalysts shows a particularly high Z-selective cyclopropanation of trisubstituted alkenes with diazoacetates. In this work, cyclic N-sulfonyl-carboxamido ligands, like saccharin and derivatives, acesulfame and a sulfahydantoin were synthesized and employed to create two-core Ru(I) complexes (like [Ru2(CO)4(µ-L)2]). As a possible solution for the problem of relative facile isomerization (head-head or head-tail constitution) of the complexes, two of the saccharin molecules were connected by a terphenyl bridge. To study the selectivity and activity of these complexes in cyclopropanation reactions, they were used as catalysts, for example in the reaction between an olefin (styrene, cyclohexene, 2-methyl-2-butene) and methyl diazoacetate. In spite of the isomerization of these complexes, a certain stereoselectivity was observable. This is expressed in higher yields of Z-cyclopropanes in case of catalysts with initially head-tail arranged ligands (especially with 6-bromosaccharin as ligand).
Date created
2011
Subject Headings
Rhodium [GND]
Ruthenium [GND]
Catalysis [LCSH]
Cyclopropane [LCSH]
Diazo compound [LCSH]
Saccharin [LCSH]
Terphenyl [LCSH]
Ruthenium [LCSH]
Keywords
Acesulfame; Bridged ligand; Carbene transfer reaction; Complex; Cyclopropanation; Head-head; Head-tail; Ligand isomerization; Sulfahydantoin
Dewey Decimal Group
DDC 540 / Chemistry & allied sciences

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Buck, Stefan (2011): Ruthenium-Sulfonamid-Komplexe als Katalysatoren für Carbenübertragungsreaktionen. Open Access Repositorium der Universität Ulm. Dissertation. http://dx.doi.org/10.18725/OPARU-1900

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