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AuthorKaiser, Achimdc.contributor.author
Date of accession2016-03-14T15:20:39Zdc.date.accessioned
Available in OPARU since2016-03-14T15:20:39Zdc.date.available
Year of creation2008dc.date.created
AbstractFully conjugated macrocycles based on oligothienyl monomers constitute a new class of materials with exciting prospects: Since they do not possess end groups that interfere with the pi system of the conjugated chain, like it is possible for oligo- and polymers, they might be considered “idealised polymers”. Their cyclic nature furthermore defines intriguing new electronic properties different to linear oligomers, and their tendency to self-assemble on ordered surfaces is a good basis for an application in molecular electronics. The work presented in this thesis can be divided into three main parts: First, the synthesis of a new, aryl-substituted oligothiophene macrocycle by using the so-called “metal template” strategy. Second, the physicochemical characterisation of oligothiophene macrocycles with different monomer units, especially by UV/Vis and fluorescence spectroscopy as well as by electrochemistry. And finally, evaluation of the molecular recognition capabilities for these macrocycles in solution.dc.description.abstract
Languageendc.language.iso
PublisherUniversität Ulmdc.publisher
LicenseStandard (Fassung vom 03.05.2003)dc.rights
Link to license texthttps://oparu.uni-ulm.de/xmlui/license_v1dc.rights.uri
Dewey Decimal GroupDDC 540 / Chemistry & allied sciencesdc.subject.ddc
LCSHMacrocyclic compoundsdc.subject.lcsh
LCSHOrganic Chemistrydc.subject.lcsh
TitlePhysicochemical properties and synthesis of oligothiophene macrocyclesdc.title
Resource typeDissertationdc.type
DOIhttp://dx.doi.org/10.18725/OPARU-1143dc.identifier.doi
PPN634566059dc.identifier.ppn
URNhttp://nbn-resolving.de/urn:nbn:de:bsz:289-vts-64614dc.identifier.urn
GNDOligothiophenedc.subject.gnd
FacultyFakultät für Naturwissenschaftenuulm.affiliationGeneral
Date of activation2008-07-08T10:44:35Zuulm.freischaltungVTS
Peer reviewneinuulm.peerReview
Shelfmark print versionZ: J-H 11.895; W: W-H 11.383uulm.shelfmark
DCMI TypeTextuulm.typeDCMI
VTS ID6461uulm.vtsID
CategoryPublikationenuulm.category
Bibliographyuulmuulm.bibliographie


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