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AuthorZiener, Ulrichdc.contributor.author
AuthorHanack, Michaeldc.contributor.author
Date of accession2016-03-14T15:20:20Zdc.date.accessioned
Available in OPARU since2016-03-14T15:20:20Zdc.date.available
Year of creation1994dc.date.created
Abstract4-tert-Butylphthalodinitrile (1) reacts with ammonium perrhenate, NH4Re04, to yield nitrido(tetra-tert-butylphthalocyaninato) rhenium(V),( tBu)4PcReN (2) , which is characterized by IR, UV/Vis, CV, MS, "H and I3C NMR, and elemental analysis. It shows good solubility in common organic solvents. In solution 2 is assumed to be monomeric whereas in the solid state also dimers or higher aggregates are present. From the NMR spectra it is concluded that different constitutional isomers of 2 are formed but not in the expected ratio of a statistical distribution. By analogy with 2, the already known nitrido(phthalocyaninato)rhenium(V), PcReN (3), is prepared for comparison.dc.description.abstract
Languageendc.language.iso
PublisherUniversität Ulmdc.publisher
ID of original publ.https://doi.org/10.1002/cber.19941270919dc.relation.uri
LicenseStandard (Fassung vom 03.05.2003)dc.rights
Link to license texthttps://oparu.uni-ulm.de/xmlui/license_v1dc.rights.uri
KeywordPhthalocyaninato complexesdc.subject
KeywordRhenium(V), nitrido(phthalocyaninat0)-dc.subject
KeywordRhenium(V), nitrido(tetra-tert-butylphtha1ocyaninato)-dc.subject
Dewey Decimal GroupDDC 540 / Chemistry & allied sciencesdc.subject.ddc
LCSHRhenium compoundsdc.subject.lcsh
TitleSynthesis and characterization of Nitrido(tetra-tert-butylphthalocyaninato)rhenium(V) and Nitrido(phthalocyaninato)rhenium(V)dc.title
Resource typeWissenschaftlicher Artikeldc.type
DOIhttp://dx.doi.org/10.18725/OPARU-1110dc.identifier.doi
PPN1646237064dc.identifier.ppn
URNhttp://nbn-resolving.de/urn:nbn:de:bsz:289-vts-60967dc.identifier.urn
GNDRheniumverbindungendc.subject.gnd
FacultyFakultät für Naturwissenschaftenuulm.affiliationGeneral
Citation of original publ.Chemische Berichte 127 (1994), S. 1681 - 1685uulm.citationOrigPub
Date of activation2007-12-09T21:54:58Zuulm.freischaltungVTS
Peer reviewjauulm.peerReview
DCMI TypeTextuulm.typeDCMI
VTS ID6096uulm.vtsID
CategoryPublikationenuulm.category
Bibliographyuulmuulm.bibliographie


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