| Author | Ziener, Ulrich | dc.contributor.author |
| Author | Hanack, Michael | dc.contributor.author |
| Date of accession | 2016-03-14T15:20:20Z | dc.date.accessioned |
| Available in OPARU since | 2016-03-14T15:20:20Z | dc.date.available |
| Year of creation | 1994 | dc.date.created |
| Abstract | 4-tert-Butylphthalodinitrile (1) reacts with ammonium perrhenate, NH4Re04, to yield nitrido(tetra-tert-butylphthalocyaninato) rhenium(V),( tBu)4PcReN (2) , which is characterized by IR, UV/Vis, CV, MS, "H and I3C NMR, and elemental analysis. It shows good solubility in common organic solvents. In solution 2 is assumed to be monomeric whereas in the solid state also dimers or higher aggregates are present. From the NMR spectra it is concluded that different constitutional isomers of 2 are formed but not in the expected ratio of a statistical distribution. By analogy with 2, the already known nitrido(phthalocyaninato)rhenium(V), PcReN (3), is prepared for comparison. | dc.description.abstract |
| Language | en | dc.language.iso |
| Publisher | Universität Ulm | dc.publisher |
| ID of original publ. | https://doi.org/10.1002/cber.19941270919 | dc.relation.uri |
| License | Standard (Fassung vom 03.05.2003) | dc.rights |
| Link to license text | https://oparu.uni-ulm.de/xmlui/license_v1 | dc.rights.uri |
| Keyword | Phthalocyaninato complexes | dc.subject |
| Keyword | Rhenium(V), nitrido(phthalocyaninat0)- | dc.subject |
| Keyword | Rhenium(V), nitrido(tetra-tert-butylphtha1ocyaninato)- | dc.subject |
| Dewey Decimal Group | DDC 540 / Chemistry & allied sciences | dc.subject.ddc |
| LCSH | Rhenium compounds | dc.subject.lcsh |
| Title | Synthesis and characterization of Nitrido(tetra-tert-butylphthalocyaninato)rhenium(V) and Nitrido(phthalocyaninato)rhenium(V) | dc.title |
| Resource type | Wissenschaftlicher Artikel | dc.type |
| DOI | http://dx.doi.org/10.18725/OPARU-1110 | dc.identifier.doi |
| PPN | 1646237064 | dc.identifier.ppn |
| URN | http://nbn-resolving.de/urn:nbn:de:bsz:289-vts-60967 | dc.identifier.urn |
| GND | Rheniumverbindungen | dc.subject.gnd |
| Faculty | Fakultät für Naturwissenschaften | uulm.affiliationGeneral |
| Citation of original publ. | Chemische Berichte 127 (1994), S. 1681 - 1685 | uulm.citationOrigPub |
| Date of activation | 2007-12-09T21:54:58Z | uulm.freischaltungVTS |
| Peer review | ja | uulm.peerReview |
| DCMI Type | Text | uulm.typeDCMI |
| VTS ID | 6096 | uulm.vtsID |
| Category | Publikationen | uulm.category |
| Bibliography | uulm | uulm.bibliographie |
